Industrial Chloroform Emissions Are Rising, and That's Bad News

A recent uptick in industrial chloroform emissions can be traced to sources in eastern China.
A recent uptick in industrial chloroform emissions can be traced to sources in eastern China.
Photo: NASA

One of the rare bright spots amidst the environmental hellscape of 2018 was a United Nations report that the ozone hole was on track to be fully healed by mid century. But because no good news comes without caveats, scientists are now reporting that overlooked emissions of chloroform, which are on the rise in East Asia, could put a bit of a damper on that recovery.


In addition to knocking people unconscious in mid-2oth century spy movies, chloroform is used in the manufacturing of various products, from Teflon to refrigerants. It’s also part of a diverse family of chlorinated substances humans produce that have the unhappy side-effect of destroying ozone, a molecule that forms a protective stratospheric shield against DNA-damaging ultraviolet light.

The primary ozone-destroying substances, called chlorofluorocarbons, were phased out under the Montreal Protocol beginning in the late 1980s. But until now, chloroform’s ability to gnaw away at our ozone layer has been largely overlooked, given its short (<6 month) lifetime in the lower atmosphere. It and other so-called very short-lived substances, namely the industrial solvent dichloromethane, aren’t regulated under the Montreal Protocol at all.

But recent research suggests that might be a bigger oversight than the protocol’s architects intended. A study published last year showed that dichloromethane concentrations are growing rapidly, with the potential to delay Antarctic ozone recovery by several decades. Now, a team of researchers from MIT, the University of Bristol, and elsewhere has confirmed that global chloroform emissions have also been on the rise lately.

Compiling data from seven atmospheric monitoring stations worldwide, the researchers found chloroform emissions rose some 3.5 percent per year from 2010 to 2015, after decades of holding steady. Using atmospheric models, the team determined that all of the emissions growth could be traced to eastern China.

Worryingly, the researchers write, weather patterns in this part of the world including the Asian monsoon “could provide efficient pathways for directly transporting air pollutants to the upper troposphere and lower stratosphere.”

In other words, chloroform emitted in East Asia may have a higher potential to deplete ozone that chloroform emitted elsewhere. If emissions continue to grow at 2010-2015 rates, the researchers estimate recovery of the ozone hole could be delayed by up to 8 years.


It’s not the first recent evidence of an uptick in ozone-destroying substances from eastern Asia. Earlier this year, researchers reported that CFC-11, a refrigerant banned under the Montreal Protocol, has been on the rise since 2012. While the exact source of those emissions remains uncertain, recent evidence points to rogue Chinese factories as a likely culprit. Other ozone-depleting substances, like carbon tetrachloride, CFC-114, and CFC-115, also aren’t declining as expected over eastern Asia, per the new study.

So far, it’s unclear whether any of these recent emissions spikes are directly related. What is clear is that the fight to stamp out ozone-annihilators isn’t won yet. And if emissions of overlooked substances like chloroform continue to grow, this environmental problem might not be solved in our lifetimes after all.


[MIT Research News]

Maddie Stone is a freelancer based in Philadelphia.


Dense non aqueous phase liquid

They may want to pinpoint those fancy satellites onto the pulp and paper industry (and water/wastewater, too). Or not. While pretty much all chloroform industrial production goes to chemicals manufacturing of refrigerants as Maddie said, a shit load of chloroform that is released to the environment comes from pulp and paper (50%), industrial chemicals manufacturing (25%), and other (5%). Releases of chloroform into the environment is chiefly via fugitive air emissions.

The thing about chemicals manufacturing, licensed or rogue, is that to run a business successfully, reactants and intermediates should be turned into final products. Not always the case given the obvious spills into the land, water and air occurring since the industrial revolution. US and Europe chemical giants did however, pretty much disassembled and reassembled a chunk of its’ halogenation processing plants throughout Asia from China to Pakistan. Thusly making Asian chemical giants and/or subsidiaries. This all started during the globalization period of the gogo 1990s.

Kids can make chloroform with parent supervision of course by adding bleach to alcohol (preferably methanol or wood alcohol). But that’s not recommended. At all. Please don’t do that.

Pulp and paper industries generate chloroform during the bleaching process. This is purely a waste product and recovery would add to shipping cost of christmas presents. Chloroform is also a product released to the atmosphere of water/wastewater chlorination for disinfection.

I checked with limited googling and chloroform production over the past 30 odd years about doubled. While that seems like a lot, it’s not much given the fact that the entire continent of Asia industrialized during that time. Lots of people in Asia.